The plane, a Tupolev Tu-154, was flying from Warsaw to the Russia city of Smolensk also carried the president's wife, army chief of staff, Deputy Foreign Minsiter Andrzej Kremer and the central bank governor, said Polish Foreign Ministry spokesman Piotr Pszkowski.
It crashed some 1.5 km from Smolensk airport in foggy weather, Russia news agencies reported.
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The Russian television's broadcast live footage showed that the plane's wreckage scattered in a forest with parts of it still on fire.
The rescuers are still searching the missing black box.
Russian President Dmitry Medvedev has sent Minister for Emergency Situations Sergei Shoigu, to the crash site and ordered the establishment of a investigation committee headed by Prime Minister Vladimir Putin to investigate the air disaster.
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Opinion
• Could air tragedy bring thaw to Russian-Polish relation?
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News
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• Russia to mourn plane crash victims: Medvedev
• Body of Polish president found in crash site
• Witnessing the scene of Polish president's plane crash
• Relatives of plane crash victims arrived in Moscow
• All 97 bodies found at crash site
• Obama expresses condolences to Poland over plane crash tragedy
• Putin flies to plane crash site to meet Polish PM
• Afghan president expresses condolence over death of Polish president
• Austrian president expresses condolences on Polish president's death
• German Chancellor sends condolences to Poland on plane crash
• French President expresses sadness at Polish plane crash
• 2 of 4 black boxes of crashed plane found
• Russian leaders send condolences to Poland on plane crash
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• 96 people on board crashed plane
• Pilot error suspected in Polish president's plane crash
• Polish president killed in plane crash in W. Russia
• 132 on board of carshed plane of polish president
• Polish president's plane crashes in W. Russia, killing all on board
Backgrounder
• Major air accidents in recent years
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